After following this mailing list for 15 years, I am very skeptical of the work published by Shanks, but I am in no position to prove it is wrong.
I am also skeptical that anybody travelling directly by car from Windsor to Montreal (post 1970) would have had to pass through multiple time zone regions.
The OSM relations are listed below.
Note that if you click on the OSM links, the colour orange is used for both inner and outer boundaries thus the inner polygons are "holes" or "excluded areas". Without shading, it is not always simple to recognize this.
The relations are large and may take some time to load in your browser.
OSM America/Toronto relation:
Includes most of Quebec and most urban centres in Ontario.
Area: 1,546,844.1 square km.
OSM America/Nipigon relation:
Includes most rural areas of Ontario east of 90°W
Also includes a few populated centers such as Sarnia (pop: 72,047) and Barrie (pop: 147,829).
Area: 787,493.2 square km.
From a daylight saving standpoint, both zones have been the same since 1974.
It would be very helpful if somebody could accurately determine when Barrie and Sarnia started using daylight saving (without using Shanks or OSM as a reference).
-chris